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Heterogeneous Artificial PSI: Photoinduced PCET in Zr-MOFs. (J. Am. Chem. Soc. 2026, 10.1021/jacs.6c02964)
Switching-Off to Switching-On Singlet–Triplet ISC in Porphyrin MOFs. (Angew. Chem. Int. Ed. 2025e202510720)
Symmetry-Breaking Charge Transfer in Metal–Organic Frameworks. (J. Am. Chem. Soc. 2024, jacs.3c13764)
Triplet Generation Through Singlet Fission in Metal-Organic Framework: An Alternative Route to Inefficient Singlet-Triplet Intersystem Crossing. (Angew. Chem. Int Ed 2023e202305323)

Framework-Topology-Controlled Singlet Fission in Metal–Organic Frameworks. (J. Am. Chem. Soc. 202310.1021/jacs.3c03918)

Decoupling Redox Hopping and Catalysis in Metal-Organic Frameworks-based Electrocatalytic CO2 Reduction. (Angew. Chem. Int Ed 2023e202219046)
Superradiance and Directional Exciton Migration in Metal–Organic Frameworks (J. Am. Chem. Soc. 2022, 144, 1396-1406)
Improving Energy Transfer within Metal-Organic Frameworks by Aligning Linker Transition Dipole along Framework Axis (J. Am. Chem. Soc. 2020, 142, 25, 11192-11202)
Wavelength-Dependent Energy and Charge Transfer in MOF: A Step towards Artificial Porous Light-Harvesting System (J. Am. Chem. Soc. 2019141, 16849-16857)
Excited-State Electronic Properties in Zr-Based Metal−Organic Frameworks as a Function of a Topological Network (J. Am. Chem. Soc. 2018, 140, 10488-10496)
Role of polar node in charge-transfer process within Zr-Based MOF (J. Am. Chem. Soc. 2018, 140, 2756-2760)
Airfree manipulation for synthesis and spectroscopy.
Spectroscopic components on the optical table.

We are located in Neckers 306/323, Department of Chemistry & Biochemistry, SIU, Carbondale, IL.

We investigate photophysical, photochemical, and electrochemical properties of porous molecular assemblies, like MOFs.

 

Group News

    • July 25, 2026: Congratulations, Dr. Saha and the group on the JACS (Artificial PSI in MOF)
    • Nov 14, 2025: Congratulations to Dr. Sreehari Surendran Rajasree on his successful thesis defense -good luck with your future journey!!
    • Aug 18, 2025: Congratulations, Dr. Saha, on his first paper from the group (decoding antenna behavior)
    • Aug 12, 2025: Congratulations, Sreehari, for switching off/on ISC in por-MOF in Angew. Chem.!
    • July 1, 2025: Congratulations to Dr. Deria on his promotion to full Professor.
    • May 7, 2024: Congratulations, Sreehari, on the Gower fellowship and Doctoral Research Assistantship (DRA).
    • Feb 14, 2024: Congratulations, Sreehari, for the SBCT in the MOF paper in JACS!
    • August 1, 2023: Congratulations, Sreehari and Jierui, on the topology-dependent SF paper published in JACS.
    • July 31, 2023: Congratulations, Sreehari, for passing his candidacy exam! way to go!
    • July 31, 2023: Congratulations, Sreehari and Jierui, on the ISC/SF paper appearing online in Angew. Chem. 
    • March 21, 2023: Congratulations, Xinlin, on the CO2 reduction paper in Angew. Chem. Int Ed.
    • March 20, 2023: Congratulations, Riya, for receiving the Willis Swartz award
    • Oct 2022: Congratulations to Dr. Xinlin Li on his successful defense -good luck with your future journey.